21,110 research outputs found

    Voltage regulator/amplifier is self-regulated

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    Signal modulated, self-regulating voltage regulator/amplifier controls the output b-plus voltage in modulated regulator systems. It uses self-oscillation with feedback to a control circuit with a discontinuous amplitude action feedback loop

    Improved electrode gives high-quality biological recordings

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    To obtain high quality waveforms from a subject engaged in physical activity, an improved electrode assembly has been devised. This consists of a cup containing an electrically conductive paste and a silver electrode. The paste maintains contact between the skin and the plate

    Computer program samples digital data for CRT display

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    High volume, multichannel data reduction computer program permits selection of the rates at which digital data is sampled. The program, written in FORTRAN 4 source language, also permits accessibility to the original mass of data

    Electrode for biological recording

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    Electrochemically reversible silver-silver chloride electrode for detecting bioelectric potential differences generated by human muscles and organ

    Bimetallic Effects on Ethylene Polymerization in the Presence of Amines: Inhibition of the Deactivation by Lewis Bases

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    Dinickel complexes supported by terphenyl ligands appended with phenoxy and imine donors were synthesized. Full substitution of the central arene blocks rotation around the aryl–aryl bond and allows for the isolation of atropisomers. The reported complexes perform ethylene polymerization in the presence of amines. The inhibiting effect of polar additives is up to 250 times lower for the syn isomer than the anti isomer. Comparisons with mononuclear systems indicate that the proximity of the metal centers leads to the observed inhibitory effect on the deactivation of the catalysts

    THE DEFICIT IN NATURAL RESOURCE RESEARCH

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    Resource /Energy Economics and Policy,

    Dinickel Bisphenoxyiminato Complexes for the Polymerization of Ethylene and α-Olefins

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    Dinuclear nickel phenoxyiminato olefin polymerization catalysts based on rigid p-terphenyl frameworks are reported. Permethylation of the central arene of the terphenyl unit and oxygen substitution of the peripheral rings ortho to the aryl–aryl linkages blocks rotation around these linkages, allowing atropisomers of the ligand to be isolated. The corresponding syn and anti dinickel complexes (25-s and 25-a) were synthesized and characterized by single-crystal X-ray diffraction. These frameworks limit the relative movement of the metal centers, restricting the metal–metal distance. Kinetics studies of isomerization of a ligand precursor (7-a) allowed the calculation of the activation parameters for the isomerization process (ΔH^‡ = 28.0 ± 0.4 kcal × mol^(–1) and ΔS^‡ = −12.3 ± 0.4 cal mol^(–1) K^(–1)). The reported nickel complexes are active for ethylene polymerization (TOF up to 3700 (mol C_2H_4) (mol Ni)^(−1) h^(–1)) and ethylene/α-olefin copolymerization. Only methyl branches are observed in the polymerization of ethylene, while α-olefins are incorporated without apparent chain walking. These catalysts are active in the presence of polar additives and in neat tetrahydrofuran. The syn and anti isomers differ in polymerization activity, polymer branching, and polymer molecular weight. For comparison, a series of mononuclear nickel complexes (26, 27-s, 27-a, 28, 30) was prepared and studied. The effects of structure and catalyst nuclearity on reactivity are discussed

    Delineation of soil temperature regimes from HCMM data

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    Evaluation of LANDSAT and Heat Capacity Mapping Mission (HCMM) data as input into National Cooperative Soil Survey is discussed. Signature classification techniques were applied to 13 May 76 LANDSAT data. LANDSAT data was overlaid with HCMM data, revealing registration problems caused by a shortage of control points in LANDSAT data, and the WARP program developed to improve registration accuracy. Initial images for control point selection were produced using digital terrain elevation data. Statistical procedures for evaluating data classification and to describe spatial distribution of surface temperature and its correlation with soil surface conditions were investigated
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